You can do so by first defining a DataTemplate for the corresponding columns as follows. Sample code can be seen with better formatting in this thread (ListView Column ToolTip)
[XAML]
<Page xmlns='http://schemas.microsoft.com/winfx/2006/xaml/presentation'
xmlns:x='http://schemas.microsoft.com/winfx/2006/xaml'>
<StackPanel>
<StackPanel.Resources>
<DataTemplate x:Key='nameTemplate'>
<TextBlock Text='{Binding Name}' Margin='-6,0'>
<TextBlock.ToolTip>
<ToolTip>
<TextBlock Foreground='Green' Text='{Binding Name}'/>
</ToolTip>
</TextBlock.ToolTip>
</TextBlock>
</DataTemplate>
<DataTemplate x:Key='namespaceTemplate'>
<TextBlock Text='{Binding Namespace}' Margin='-6,0'>
<TextBlock.ToolTip>
<ToolTip>
<TextBlock Foreground='Green' Text='{Binding Namespace}'/>
</ToolTip>
</TextBlock.ToolTip>
</TextBlock>
</DataTemplate>
</StackPanel.Resources>
<ListView>
<ListView.ItemContainerStyle>
<Style TargetType='ListViewItem'>
<Setter Property='HorizontalContentAlignment' Value='Stretch'/>
<Setter Property='VerticalContentAlignment' Value='Stretch'/>
</Style>
</ListView.ItemContainerStyle>
<ListView.View>
<GridView>
<GridViewColumn CellTemplate='{StaticResource nameTemplate}' Width='300' Header='Name'/>
<GridViewColumn CellTemplate='{StaticResource namespaceTemplate}' Width='300' Header='Namespace'/>
</GridView>
</ListView.View>
<x:Type TypeName='Visual'/>
<x:Type TypeName='FrameworkElement'/>
<x:Type TypeName='FrameworkContentElement'/>
</ListView>
</StackPanel>
</Page>
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