The sidebar layout cannot be changed. But it can be hidden by setting DisplaySideBar property to False.
<asp:Wizard ID='Wizard1' runat='server' ActiveStepIndex='0'
BackColor='#FFFBD6' BorderColor='#FFDFAD' BorderWidth='1px' CellPadding='5'
Font-Names='Verdana' Font-Size='0.8em' Width='347px' DisplaySideBar='False'>
</asp:Wizard>
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